(1E)-1-[4-(Dimethylamino)phenyl]pent-1-en-3-one

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(1E)-1-[4-(Dimethyl­amino)phen­yl]pent-1-en-3-one

The title mol-ecule, C(13)H(17)NO, is close to planar: the dihedral angle betweent the dimethyl amino group and the benzene ring is 7.94 (19)°. No significant inter-molecular inter-actions are observed in the crystal structure.

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4-[(1E)-3-(2,6-Dichloro-3-fluoro­phen­yl)-3-oxoprop-1-en-1-yl]benzonitrile

In the title mol-ecule, C(16)H(8)Cl(2)FNO, the benzene rings form a dihedral angle of 78.69 (8)°. The F atom is disordered over two positions in a 0.530 (3):0.470 (3) ratio. The crystal packing exhibits π-π inter-actions between dichloro-substituted rings [centroid-centroid distance = 3.6671 (10) Å] and weak inter-molecular C-H⋯F contacts.

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(E)-3-(4-Heptyl­oxyphen­yl)-1-phenyl­prop-2-en-1-one

In the title compound, C22H26O2, the aromatic rings are inclined to one another by 8.39 (9)° and the mol-ecule has an E conformation about the C=C bond. In the crystal, mol-ecules stack head-to-tail along the b-axis direction. They are linked by very weak C-H⋯O contacts, forming C(4) chains along [100]. Two chains are linked by a pair of very weak C-H⋯O contacts, enclosing inversion-dimeric R 2...

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1-(4-Chloro­phen­yl)-4,4-dimethyl­pent-1-en-3-one

In the title compound, C(13)H(15)ClO, the carbonyl and ethenyl groups are not coplanar with benzene ring system, forming dihedral angles of 35.37 (5) and 36.27 (11)°, respectively. The mol-ecules are packed in an offset face-to-face arrangement showing π-π stacking inter-actions involving the benzene rings [centroid-centroid distance = 3.586 (4) Å].

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3-Dimethyl­amino-1-(4-methyl­phen­yl)prop-2-en-1-one

In the title compound, C(12)H(15)NO, the C=C and C=O functional groups and the benzene ring are involved in an extended conjugated system. The mol-ecules are essentially planar with a maximal deviation from planarity for the non-H atoms of 0.062 (2) Å.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809046972